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Yang, W.T.; Zhang, Y.K.; Ayers, P.W. Degenerate surface claims and you may an excellent fractional amount of electrons inside occurrence and you can reduced density matrix useful principle. In other words, the brand new importance of your magnitudes of revolves to your setup is also become relocated to high-acquisition connections whenever supposing the brand new magnitudes away from revolves getting lingering. Such “artificial” higher-acquisition terms, only emerging for compensating to possess such configuration dependence, are not most actual but can a bit improve the suitable shows . Inside the Ref. , to the four Mn sites inside a great device cellphone out of YMnO3, the brand new polar and azimuthal angles (θ,φ) of their revolves are supplied because of the , , (θ,3π2), and you will (θ,π2), respectively. Because of the altering the fresh θ from 0° to 180°, additional setup are made. Such a deviation is actually well treated adding biquadratic replace connections for the productive Hamiltonian model.
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